Search results for "digital simulation"

showing 7 items of 7 documents

A quantum mechanics-molecular mechanics study of dissociative electron transfer : The methylchloride radical anion in aqueous solution

2002

The dissociative electron transfer reaction CH3Cl+e−→CH3•+Cl− in aqueous solution is studied by using a QM/MM method. In this work the quantum subsystem (a methylchloride molecule plus an electron) is described using density functional theory while the solvent (300 water molecules) is described using the TIP3P classical potential. By means of molecular dynamics simulations and the thermodynamic integration technique we obtained the potential of mean force (PMF) for the carbon–chlorine bond dissociation of the neutral and radical anion species. Combining these two free energy curves we found a quadratic dependence of the activation free energy on the reaction free energy in agreement with Ma…

Aqueous solutionChemistryGeneral Physics and AstronomyThermodynamic integrationFree radicalsMolecular dynamics methodOrganic compounds ; Dissociation ; Charge exchange ;Free radicals ; Negative ions ; Molecular dynamics method ; Digital simulationKinetic energyNegative ionsUNESCO::FÍSICA::Química físicaMolecular dynamicsElectron transferQuantum mechanicsOrganic compoundsMoleculeDensity functional theoryPhysical and Theoretical ChemistryPotential of mean forcePhysics::Chemical PhysicsCharge exchangeDigital simulation:FÍSICA::Química física [UNESCO]Dissociation
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Il Filtro Integrale Auto-Regressivo Continuo (I-ARC) per l’Analisi di Strutture Esposte al Vento

2010

In questo studio viene proposto un metodo per la rappresentazione di processi aleatori Gaussiani e stazionari, utile a modellare la turbolenza della velocità del vento, introducendo la versione integrale del modello auto-regressivo discreto già proposto in precedenza. La rappresentazione di un processo aleatorio di assegnata funzione di correlazione viene condotta integrando un’equazione integro-differenziale in cui viene coinvolto un nucleo, che rappresenta la memoria del processo, in presenza di un rumore bianco Gaussiano. La soluzione dell’equazione rappresenta un campione del processo aleatorio della turbolenza della velocità del vento. E’ stato mostrato che il modello I-ARC fornisce, n…

Digital simulation Autoregressive-Continuous Filters Gaussian Processes Stochastic Differential Calculus.Settore ICAR/08 - Scienza Delle Costruzioni
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Climate change impact on SWAT simulated streamflow in western Kenya

2009

12 pages (3/4 p.); International audience; Weather and climate extremes such as droughts and floods have far reaching impacts in Kenya. They have had implications in a variety of sectors including agriculture, water resources, health, energy, and disaster management among others. Lake Victoria and its catchment support millions of people and any impact on its ability to support the livelihoods of the communities in this region is of major concern. Thus, the main objective of this study was to assess the potential future climatic changes on the Nzoia catchment in the Lake Victoria basin, and how they might affect streamflow. The Soil and Water Assessment Tool was used to investigate the impa…

Dynamical climatologyrunoffhydrologyLake VictoriaEast AfricaKenyaHydroclimatologyImpact studyatmospheric precipitation[SDE.MCG] Environmental Sciences/Global Changes[ SDE.MCG ] Environmental Sciences/Global Changes[SDU.STU.CL] Sciences of the Universe [physics]/Earth Sciences/Climatologyclimate changeRainfall rateAfricaForecast modeldigital simulationdrainage basinsEast African Lakesstreamflow[ SDU.STU.CL ] Sciences of the Universe [physics]/Earth Sciences/Climatologyriver dischargeglobal change
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Monte Carlo simulation for the response analysis of long-span suspended cables under wind loads

2004

This paper presents a time-domain approach for analyzing nonlinear random vibrations of long-span suspended cables under transversal wind. A consistent continuous model of the cable, fully accounting for geometrical nonlinearities inherent in cable behavior, is adopted. The effects of spatial correlation are properly included by modeling wind velocity fluctuation as a random function of time and of a single spatial variable ranging over cable span, namely as a one-variate bi-dimensional (1V-2D) random field. Within the context of a Galerkin`s discretization of the equations governing cable motion, a very efficient Monte Carlo-based technique for second-order analysis of the response is prop…

EngineeringRandom fieldDiscretizationSuspended cablebusiness.industrysuspended cable; wind velocity random field; Proper Orthogonal DecompositionMonte Carlo methodRandom functionBuilding and ConstructionMechanicsStructural engineeringAerodynamicsProper orthogonal decompositionWind speedVibrationNonlinear systemModeling and SimulationWind velocityRandom fieldNonlinear vibrationDigital simulationbusinessCivil and Structural EngineeringWind and Structures
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Fractional Spectral Moments for Digital Simulation of Multivariate Wind Velocity Fields

2012

In this paper, a method for the digital simulation of wind velocity fields by Fractional Spectral Moment function is proposed. It is shown that by constructing a digital filter whose coefficients are the fractional spectral moments, it is possible to simulate samples of the target process as superposition of Riesz fractional derivatives of a Gaussian white noise processes. The key of this simulation technique is the generalized Taylor expansion proposed by the authors. The method is extended to multivariate processes and practical issues on the implementation of the method are reported.

FOS: Computer and information sciencesMultivariate wind velocity fieldMultivariate statisticsStatistical Mechanics (cond-mat.stat-mech)Fractional spectral momentRenewable Energy Sustainability and the EnvironmentMechanical EngineeringMathematical analysisFOS: Physical sciencesGeneralized Taylor formWhite noiseFunction (mathematics)Digital simulation of Gaussian stationary processeFractional calculuStatistics - ComputationTransfer functionWind speedFractional calculusSuperposition principleSettore ICAR/08 - Scienza Delle CostruzioniComputation (stat.CO)Condensed Matter - Statistical MechanicsLinear filterCivil and Structural EngineeringMathematics
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Requirements for using simulation to design and assess wireless ATM handover solutions

1999

Wireless ATM (WATM) has been widely considered as a solution for broadband wireless services. Handover is one of the most important mobility support functions in the WATM network. Many handover solutions have been proposed, analysed, and benchmarked. Simulations have been broadly used to assess these solutions. However, there are many dilemmas in how simulation has been applied as a research methodology: heterogeneous simulation systems used, lack of comparison with other related work, biased conclusions, and unavailability of simulation models and systems to researchers. The WATM research community lacks a standard and commonly acceptable methodology for applying simulation. To address thi…

land mobile radiowireless ATM handover solutionsasynchronous transfer modebroadband networksComputerSystemsOrganization_COMPUTER-COMMUNICATIONNETWORKSWATMhandover simulation modelanalytical modelsdigital simulationsimulation modelsmobility support functionsheterogeneous simulation systemsbroadband wireless
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Fractional calculus approach for the representation of power spectral densities and correlation functions in wind engineering

2010

The paper deals with the digital simulation of wind velocity samples by Fractional Spectral Moment function. It is shown that such a function represents a third useful way to characterize a stationary Gaussian stochastic process, alongside the power spectral density and the correlation function. The method is applied to wind velocity fields whose power spectra is given by the Kaimal’s, the Davenport’s and the Solari’s representation. It is shown that by constructing a digital filter whose coefficients are the fractional spectral moments, it is possible to simulate samples of the target process as superposition of Riesz fractional derivatives of Gaussian white noise processes.

wind velocity fieldfractional spectral momentgeneralized Taylor formDigital Simulation
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